The molex cable has both 12v and 5v power available, it's limited by the wire size as the psu should be able to provide over 20 amps to the cable. Most psu's use 18ga wire and that should handle 8-10 amps, more than that it starts to get hot, connectors can be a issue sometimes, look for any corrosion on the pins. I can't see the pump pulling so much power to trip the PSU unless the pump is defective. If it trips from running the "Reset maximum pump speed" that sounds more software related but I don't know how it could overload the PSU.