For me it seem that your GPU2 does not have good enough contact with the cooler.
I have the same waterblock, with an Sapphire HD5970 OC.
I run watertemps of 40/44 idle and 61/61 at full stress.
The GPU VRM, runs at 42/43 idle, 72/79 at ful stress
Chrech if you can get a better fit for GPU2.
drbo
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